Neutral zinc–iron flow batteries (ZIFBs) remain attractive due to features of low cost, abundant reserves, and mild operating medium. However, the ZIFBs based on Fe (CN) 63– /Fe (CN) 64– catholyte suffer from Zn 2 Fe (CN) 6 precipitation due to the Zn 2+ crossover from the anolyte.
Among which, zinc-iron (Zn/Fe) flow batteries show great promise for grid-scale energy storage. However, they still face challenges associated with the corrosive and environmental pollution of acid and alkaline electrolytes, hydrolysis reactions of iron species, poor reversibility and stability of Zn/Zn 2+ redox couple.
Authors to whom correspondence should be addressed. Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical energy storage technology due to their low electrolyte cost.
The ultralow cost neutral Zn/Fe RFB shows great potential for large scale energy storage. Zinc-based flow batteries have attracted tremendous attention owing to their outstanding advantages of high theoretical gravimetric capacity, low electrochemical potential, rich abundance, and low cost of metallic zinc.
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Download Citation | On Sep 26, 2023, Yukun Xie and others published Optimal Design of Zinc-iron Liquid Flow Battery Based on Flow Control | Find, read and cite all the research you need …
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This study breaks the solid-liquid working mode of the Zn anode, offering an effective solution for LDES applications with Zn-FBs. A liquid metal electrode enables dendrite-free, zinc-based …
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Neutral zinc–iron flow batteries face five key challenges: Zn dendrite formation, hydrogen evolution reaction, ion crossover, low catholyte solubility, and ion hydrolysis. These …
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Neutral zinc-iron flow batteries (ZIFBs) remain attractive due to features of low cost, abundant reserves, and mild operating medium. However, the ZIFBs based on Fe (CN) 63- …
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Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical energy storage technology due to their low …
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Abstract Zinc-based flow batteries have attracted tremendous attention owing to their outstanding advantages of high theoretical gravimetric capacity, low electrochemical …
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Zinc- based flow batteries (Zn- FBs) are promising candidates for large- scale energy storage because of their intrin-sic safety and high energy density. Unlike that …
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Zinc-iron liquid flow batteries have high open-circuit voltage under alkaline conditions and can be cyclically charged and discharged for a long time under high current …
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Aqueous zinc-iodine flow batteries show potential in large-scale storage but face water imbalance-induced instability. Here, authors develop a tailored ionic-molecular sieve …
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Neutral zinc–iron flow batteries (ZIFBs) remain attractive due to features of low cost, abundant reserves, and mild operating medium. …
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Neutral zinc–iron flow batteries (ZIFBs) remain attractive due to features of low cost, abundant reserves, and mild operating medium. However, the ZIFBs based on Fe (CN) …
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Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical …
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